文献详情
Noble metal-free hydrogen evolution catalysts for water splitting
文献类型期刊
作者Zou, Xiaoxin[1];Zhang, Yu[2]
机构
2015
通讯作者Zhang, Y (reprint author), Beihang Univ, Key Lab Bioinspired Smart Interfacial Sci & Tech, Beijing Key Lab Bioinspired Energy Mat & Devices, Minist Educ,Sch Chem & Environm, Beijing 100191, Peoples R China.
期刊名称CHEMICAL SOCIETY REVIEWS影响因子和分区
来源信息年:2015  卷:44  期:15  页码范围:5148-5180  
44
期刊信息CHEMICAL SOCIETY REVIEWS影响因子和分区  ISSN:0306-0012
15
页码范围5148-5180
增刊正刊
摘要Sustainable hydrogen production is an essential prerequisite of a future hydrogen economy. Water electrolysis driven by renewable resource-derived electricity and direct solar-to-hydrogen conversion based on photochemical and photoelectrochemical water splitting are promising pathways for sustainable hydrogen production. All these techniques require, among many things, highly active noble metal-free hydrogen evolution catalysts to make the water splitting process more energy-efficient and economical. In this review, we highlight the recent research efforts toward the synthesis of noble metal-free electrocatalysts, especially at the nanoscale, and their catalytic properties for the hydrogen evolution reaction (HER). We review several important kinds of heterogeneous non-precious metal electrocatalysts, including metal sulfides, metal selenides, metal carbides, metal nitrides, metal phosphides, and heteroatom-doped nanocarbons. In the discussion, emphasis is given to the synthetic methods of these HER electrocatalysts, the strategies of performance improvement, and the structure/composition-catalytic activity relationship. We also summarize some important examples showing that non-Pt HER electrocatalysts could serve as efficient cocatalysts for promoting direct solar-to-hydrogen conversion in both photochemical and photoelectrochemical water splitting systems, when combined with suitable semiconductor photocatalysts.
收录情况SCIE(WOS:000358219300009)  ESI高被引论文(000358219300009)  ESI热点论文(000358219300009)  
所属部门化学学院
DOI10.1039/c4cs00448e
重要成果类型ESI热点;ESI高被引
百度学术Noble metal-free hydrogen evolution catalysts for water splitting
语言外文
ISSN0306-0012
被引频次15521552
人气指数258
浏览次数258
基金Jilin University; fundamental research funds for the central universities; National Natural Science Foundation of China [51372007, 21301014, 21401066]; Jilin province science and technology development projects [20150520003JH]
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