文献详情
Evolution of the formation of a covalent triazinebased framework catalyzed by p-toluenesulfonic acid monohydrate
文献类型期刊
作者Li, Zheng[1];Han, Yue[2];Guo, Ying[3];Xu, Shuangshuang[4];Chen, Fenghua[5];Ye, Li[6];Luo, Zhenhua[7];Liu, Xiang[8];Zhou, Heng[9];Zhao, Tong[10]
机构
2017
期刊名称RSC ADVANCES影响因子和分区
通讯作者Zhou, H; Zhao, T (reprint author), Chinese Acad Sci, Inst Chem, Lab Adv Polymer Mat, Beijing 100190, Peoples R China.; Zhou, H; Zhao, T (reprint author), Univ Chinese Acad Sci, Beijing 100049, Peoples R China.
7
来源信息年:2017  卷:7  期:72  页码范围:45818-45823  
72
期刊信息RSC ADVANCES影响因子和分区  ISSN:2046-2069
页码范围45818-45823
增刊正刊
摘要A porous covalent triazine-based framework (CTF) was prepared by a two-step strategy, where ptoluenesulfonic acid monohydrate (TsOH center dot H2O) was used as a catalyst. The porosity and gas storage capacity of the as-obtained framework was evaluated. In addition, the evolution of the chemical structure during the two stages was studied. Crystallite size was calculated to study the formation of the framework; the evolution of internal porosity has been discussed based on the results obtained. In the first step, a triazine-based polymer was formed at relatively low temperatures, and limited crystallites were developed. However, in the second step, a treatment at higher temperatures performed in an open system resulted in the purification of the chemical structure; furthermore, CTF lamellae with an improved ordered stacking developed, resulting in a dramatic increase in internal porosity.
收录情况SCIE(WOS:000412147000067)  
所属部门材料科学与工程学院
DOI10.1039/c7ra07181g
学科化学综合
百度学术Evolution of the formation of a covalent triazinebased framework catalyzed by p-toluenesulfonic acid monohydrate
语言外文
ISSN2046-2069
人气指数239
浏览次数239
基金National Natural Science Foundation of China [51403218, 51473171, 21604090]; Young Elite Scientist Sponsorship Program by CAST; Youth Innovation Promotion Association of CAS [2017047]
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